Composites Containing Nanostructured Shape-Memory Alloys

Capabilities for tailoring material properties for new uses are under development.

A continuing program of research is devoted to understanding composite materials that include nanostructured shape-memory alloy (SMA) constituents and to developing methods of fabricating components from such materials. This research is intended to improve the utilization of SMAs in microscopic structures and miniaturized devices.

Composite materials that include SMAs afford the opportunity to investigate a variety of host-guest interactions at both molecular and bulk levels. In this research, SMAs have been combined with various polymeric and metal host matrix materials, and a variety of techniques for preparation and characterization have been used to determine the extent to which each component of each composite influences the other. New techniques for producing SMA particles that are very small but still exhibit shape memory and pseudoelasticity have been developed. The composite materials studied in this program have shown promising fracture-toughness behavior. Such studies could, potentially, yield adaptive composite materials and components made from such materials in which the SMA constituents can be used to actively or passively control material and structural properties.

The main issues addressed in this research have been the following:

  • Mechanical rolling and folding for producing SMA nanoparticles and SMA composite materials,
  • The influence of grain refinement and cold working on the mechanical behavior of nanostructured SMAs produced by mechanical alloying, and
  • Optimization of chemical functionalization for tailoring the adhesion of SMA particles in a composite matrix.

A separate part of this research has been concerned with manipulation, by use of magnetic fields, of individual nanowires with nickel end caps. Such manipulation can be useful for positioning samples and may, potentially, be useful as a means of utilizing nanowire-based devices as optical switches.

This work was done by Wendy C. Crone, Arthur B. Ellis, and John H. Perepezko of the University of Wisconsin for the Air Force Office of Scientific Research.

AFRL-0083



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Composites Containing Nanostructured Shape-Memory Alloys

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Defense Tech Briefs Magazine

This article first appeared in the October, 2008 issue of Defense Tech Briefs Magazine (Vol. 2 No. 5).

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Overview

The document is a final performance report on research conducted on nanostructured shape memory alloys (SMAs) and their application in adaptive composite materials and components. Authored by Wendy C. Crone, Arthur B. Ellis, and John H. Perepezko from the University of Wisconsin-Madison, the report was prepared for the Air Force Office of Scientific Research (AFOSR) and covers the project period from April 1, 2004, to September 30, 2007.

The research focuses on the fabrication methods for creating composite materials that incorporate shape memory alloy constituents. Various techniques were explored, including mechanical rolling methods, to produce SMA-polymer and SMA-metal composites. A significant aspect of the study was the development of new fabrication strategies aimed at producing NiTi (Nickel-Titanium) and CuAlNi (Copper-Aluminum-Nickel) shape memory alloy particles with refined sizes, which retain their shape memory and pseudoelastic properties.

The report highlights the promising fracture toughness behavior of the composite materials developed during the research. A key innovation discussed is a functionalization strategy that enhances adhesion between the shape memory alloy constituents and the polymeric matrix, allowing for tunable control over the interface properties. This advancement is crucial for improving the performance and reliability of the composite materials in practical applications.

Additionally, the research delves into the manipulation and control of individual liberated nanowires using nickel end caps and magnetic fields. This technique has enabled precise sample positioning for characterization and has facilitated optical switching behavior, showcasing the versatility and potential of these materials in advanced technological applications.

The report also notes that the research has inspired several educational projects, indicating a broader impact on public science education. Overall, the findings contribute to the understanding and development of adaptive composite materials, with implications for various fields, including aerospace and materials science.

In summary, this document encapsulates significant advancements in the fabrication and application of nanostructured shape memory alloys, emphasizing their potential in creating innovative composite materials with enhanced properties and functionalities.