Novel Active Transient Cooling Systems

Magnetic refrigeration systems offer good potential to reduce global energy consumption and use of ozone-depleting compounds, greenhouse gases, and hazardous chemicals.

Energy-efficient cooling technology is extremely important in today’s society, considering the need for energy conservation and the urgent need to mitigate global warming. Near-room-temperature magnetic refrigeration is an emerging cooling technology that has several advantages compared to conventional gas-compression technology. It utilizes the magnetocaloric effect (MCE) in which heating and cooling of a magnetocaloric material (MCM) is induced by a varying external magnetic field. The magnetocaloric effect (the temperature change of a magnetic material due to the application of an external magnetic field) is the cornerstone of magnetic cooling.

MCE is the vital element of near-room-temperature magnetic cooling, which is poised for commercialization in the future. In addition, MCE is intrinsic to every magnetic solid and is of fundamental importance; it is related to diverse topics such as spin dynamics and physical properties such as thermal conductivity.

Schematic representation of a Magnetic Refrigeration Cycle in which heat is transported from the heat load to its surroundings.
In a magnetic material, entropy is a combination of contributions from the lattice as well as from electronic and magnetic spins. Upon an adiabatic application of an external magnetic field, the magnetic spins align parallel to the field, which causes the magnetic part of the entropy to decrease. The lattice entropy consequently increases, leading to a temperature rise in the material. This heat is removed from the material to its surroundings by a heat-transfer medium (depending on the operating temperature, the heat-transfer medium may be water or air, and for very low temperatures, helium). When the field is removed under adiabatical conditions, the magnetic material cools down to below ambient temperature due to an increase in disorder of the magnetic spins; this results in lower lattice entropy.

Fe80-xGdxCr8B12 alloys exhibit good magnetocaloric properties near room temperature. Gd, which is well-known to exhibit good magnetocaloric effects in room temperature, was alloyed in Fe-Cr-B base alloys. The increase of Gd additions displaces the Curie temperature of the alloy to higher temperatures. Because of this, the experimental investigation of magnetocaloric effects and structural properties of Fe80-xGdxCr8B12 (x = 0, 5, 8, 15) alloys has been studied.

Gd addition decreases the peak entropy change slightly and displaces TC to higher temperatures. The RC values of Fe80-xGdxCr8B12 alloys compare favorably to those in GMCE materials, and the alloys are much cheaper than

the rare-earth-based MCM. The universal curve models are applicable to the studied alloys. The exponent, n, controlling the field dependence of the magnetic entropy change enables easier MCE extrapolations of the alloys at different magnetic fields.

This work was done by Raju Ramanujan of Nanyang Technological University, Singapore, for the Asian Office of Aerospace Research and Development. For more information, download the Technical Support Package (free white paper) at www.defensetechbriefs.com/tsp  under the Physical Sciences category. AFRL-0168



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Novel Active Transient Cooling Systems

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Defense Tech Briefs Magazine

This article first appeared in the December, 2010 issue of Defense Tech Briefs Magazine (Vol. 4 No. 6).

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Overview

The document is a final technical report on a research project titled "Novel Active Transient Cooling Systems," led by Principal Investigator R.V. Ramanujan and co-investigators from various institutions. The project, funded by the Asian Office of Aerospace Research & Development (AOARD), focuses on the study of magnetocaloric nanomaterials for solid-state cooling applications, which are increasingly important for energy efficiency and environmental sustainability.

The report emphasizes the significance of energy-efficient cooling technologies in addressing global energy consumption and mitigating climate change. It introduces magnetic refrigeration as an emerging technology that utilizes the magnetocaloric effect (MCE), where the temperature of a magnetic material changes in response to an external magnetic field. This method offers several advantages over traditional gas-compression refrigeration, including higher efficiency, lower operating costs, and the elimination of ozone-depleting substances.

The research specifically investigates the synthesis, characterization, and property evaluation of Fe80-xGdxCr8B12 alloys, where Gadolinium (Gd) is alloyed with iron, chromium, and boron. The study finds that these alloys exhibit favorable magnetocaloric properties near room temperature, with Gd enhancing the materials' performance by increasing the Curie temperature without significantly degrading the magnetic entropy change. The report also discusses a phenomenological model that effectively describes the magnetic entropy change in these alloys.

The document outlines the historical context of magnetic refrigeration, tracing its origins back to the late 19th century and highlighting key advancements, including the demonstration of cooling at low temperatures and the development of giant magnetocaloric effects (GMCE) in specific materials. The report notes that while magnetic refrigeration has shown promise, its widespread adoption has been limited by the availability of suitable materials that exhibit large MCE at low magnetic fields.

In conclusion, the report underscores the potential of magnetocaloric materials in revolutionizing cooling technologies, contributing to energy conservation, and reducing reliance on harmful refrigerants. The findings from this research could pave the way for more sustainable cooling solutions in various applications, aligning with global efforts to combat climate change and promote energy efficiency.