New Solid-State Battery Design Charges in Minutes

The research is an important step toward more practical solid-state batteries for industrial and commercial applications.

Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) have developed a new lithium metal battery that can be charged and discharged at least 6,000 times — more than any other pouch battery cell — and can be recharged in a matter of minutes.

Published in Nature Materials, the research not only describes a new way to make solid state batteries with a lithium metal anode but also offers new understanding into the materials used for these potentially revolutionary batteries.

“Lithium metal anode batteries are considered the holy grail of batteries because they have ten times the capacity of commercial graphite anodes and could drastically increase the driving distance of electric vehicles,” said Xin Li, Associate Professor of Materials Science at SEAS and senior author of the paper. “Our research is an important step toward more practical solid state batteries for industrial and commercial applications.”

One of the biggest challenges in the design of these batteries is the formation of dendrites on the surface of the anode. These structures grow like roots into the electrolyte and pierce the barrier separating the anode and cathode, causing the battery to short or even catch fire.

These dendrites form when lithium ions move from the cathode to the anode during charging, attaching to the surface of the anode in a process called plating. Plating on the anode creates an uneven, non-homogeneous surface, like plaque on teeth, and allows dendrites to take root. When discharged, that plaque-like coating needs to be stripped from the anode and when plating is uneven, the stripping process can be slow and result in potholes that induce even more uneven plating in the next charge.

In 2021, Li and his team offered one way to deal with dendrites by designing a multilayer battery that sandwiched different materials of varying stabilities between the anode and cathode. This multilayer, multi-material design prevented the penetration of lithium dendrites not by stopping them altogether, but rather by controlling and containing them.

In this new research, Li and his team stop dendrites from forming by using micron-sized silicon particles in the anode to constrict the lithiation reaction and facilitate homogeneous plating of a thick layer of lithium metal.

In this design, when lithium ions move from the cathode to the anode during charging, the lithiation reaction is constricted at the shallow surface and the ions attach to the surface of the silicon particle but don’t penetrate further. This is markedly different from the chemistry of liquid lithium ion batteries in which the lithium ions penetrate through deep lithiation reaction and ultimately destroy silicon particles in the anode.

But, in a solid-state battery, the ions on the surface of the silicon are constricted and undergo the dynamic process of lithiation to form lithium metal plating around the core of silicon.

“In our design, lithium metal gets wrapped around the silicon particle, like a hard chocolate shell around a hazelnut core in a chocolate truffle,” said Li. These coated particles create a homogenous surface across which the current density is evenly distributed, preventing the growth of dendrites. And, because plating and stripping can happen quickly on an even surface, the battery can recharge in only about 10 minutes.

The researchers built a postage stamp-sized pouch cell version of the battery, which is 10 to 20 times larger than the coin cell made in most university labs. The battery retained 80 percent of its capacity after 6,000 cycles. The technology has been licensed through Harvard Office of Technology Development to Adden Energy, a Harvard spinoff company cofounded by Li and three Harvard alumni. The company has scaled up the technology to build a smart phone-sized pouch cell battery.

For more information, contact Leah Burrows at This email address is being protected from spambots. You need JavaScript enabled to view it.; 617-496-1351.